International Chemical Safety Cards

NICKEL SULFIDE ICSC: 0928
NICKEL SULFIDE
Heazlewoodite
Nickel subsulphide
Trinickel disulfide
Ni3S2
Molecular mass: 240.19
CAS # 12035-72-2
RTECS # QR9800000
ICSC # 0928
EC # 028-007-00-4

TYPES OF
HAZARD/
EXPOSURE
ACUTE HAZARDS/
SYMPTOMS
PREVENTION FIRST AID/
FIRE FIGHTING
FIRE Gives off irritating or toxic fumes (or gases) in a fire.

In case of fire in the surroundings: all extinguishing agents allowed.
EXPLOSION

In case of fire: keep drums, etc., cool by spraying with water.
EXPOSURE
PREVENT DISPERSION OF DUST! AVOID ALL CONTACT!

  • INHALATION
  • Cough. Sore throat.
    Ventilation, local exhaust, or breathing protection.
    Fresh air, rest.
  • SKIN

  • Protective gloves. Protective clothing.
    Remove contaminated clothes. Rinse and then wash skin with water and soap.
  • EYES

  • Safety spectacles, or eye protection in combination with breathing protection.
    First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then take to a doctor.
  • INGESTION


  • Rest. Refer for medical attention.
    SPILLAGE DISPOSAL STORAGE PACKAGING & LABELLING
    Sweep spilled substance into containers; if appropriate, moisten first to prevent dusting. Carefully collect remainder, then remove to safe place (extra personal protection: complete protective clothing including self-contained breathing apparatus).


    T symbol
    R: 49-43
    S: 53-45
    SEE IMPORTANT INFORMATION ON BACK
    ICSC: 0928 Prepared in the context of cooperation between the International Programme on Chemical Safety & the Commission of the European Communities © IPCS CEC 1993

    International Chemical Safety Cards

    NICKEL SULFIDE ICSC: 0928

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    PHYSICAL STATE; APPEARANCE:
    PALE YELLOWISH BRONZE LUMPS WITH METALLIC LUSTRE.

    PHYSICAL DANGERS:


    CHEMICAL DANGERS:
    The substance decomposes on heating to high temperatures producing sulphur oxides.

    OCCUPATIONAL EXPOSURE LIMITS (OELs):
    TLV (as nickel): 1 mg/m3 (as TWA) A1 (ACGIH 1997).


    ROUTES OF EXPOSURE:
    The substance can be absorbed into the body by inhalation of its aerosol.

    INHALATION RISK:


    EFFECTS OF SHORT-TERM EXPOSURE:


    EFFECTS OF LONG-TERM OR REPEATED EXPOSURE:
    Repeated or prolonged contact may cause skin sensitization. This substance is carcinogenic to humans.
    PHYSICAL
    PROPERTIES
    Melting point: 790░C
    Relative density (water = 1): 5.82
    Solubility in water: none
    ENVIRONMENTAL
    DATA

    N O T E S
    Depending on the degree of exposure, periodic medical examination is indicated. Do NOT take working clothes home.
    ADDITIONAL INFORMATION


    ICSC: 0928 NICKEL SULFIDE
    © IPCS, CEC, 1993
    IMPORTANT LEGAL NOTICE: Neither the CEC or the IPCS nor any person acting on behalf of the CEC or the IPCS is responsible for the use which might be made of this information. This card contains the collective views of the IPCS Peer Review Committee and may not reflect in all cases all the detailed requirements included in national legislation on the subject. The user should verify compliance of the cards with the relevant legislation in the country of use.